[DFTB-Plus-User] ​Re: Failure in diagonalisation routine ZHEEVR for Li-S systems

Wu, Qisheng qisheng_wu at brown.edu
Tue Nov 29 20:13:18 CET 2022


Dear Bálint and Martin,

I have identified the reason for this error by carefully double-checking my
calculations again and again. Basically, I assumed the same content for
Li-S.skf and S-Li.skf but actually, it's not the case. I always copied
Li-S.skf as S-Li.skf, which is why I constantly got errors while doing
calculations with the standalone DFTB+ code.

Your time and responses are much appreciated. Sorry for this stupid
mistake, but I hope the same error can be avoided by other people when
doing DFTB calculations.

Thanks again.

Best regards,
Qisheng Wu



> ----------------------------------------------------------------------
>
> Message: 1
> Date: Tue, 22 Nov 2022 09:14:20 -0500
> From: "Wu, Qisheng" <qisheng_wu at brown.edu>
> To: dftb-plus-user at mailman.zfn.uni-bremen.de
> Subject: Re: [DFTB-Plus-User]  Failure in diagonalisation routine
>         ZHEEVR for Li-S systems
> Message-ID:
>         <CAPhmeq2AArP1E7V4+WnpjC9Y6L=__8=
> f7esniHQL4uHvyqQ-YA at mail.gmail.com>
> Content-Type: text/plain; charset="utf-8"
>
> Dear Bálint,
> Thanks a lot for clarifying this. I do not want to do anything crazy.
>
> Best regards,
> Qisheng Wu
>
>
>
> > From: Bálint Aradi <aradi at uni-bremen.de>
> > To: dftb-plus-user at mailman.zfn.uni-bremen.de
> > Subject: Re: [DFTB-Plus-User]  Failure in diagonalisation routine
> >         ZHEEVR for Li-S systems
> > Message-ID: <dcccea4c-258e-0679-e807-aced1392d70b at uni-bremen.de>
> > Content-Type: text/plain; charset="utf-8"; Format="flowed"
> >
> > Dear Qisheng Wu,
> >
> > you should never treat the maximal angular momenta as fitting
> > parameters. (Actually, we have them in the user input only for
> > historical reasons, I'd like to remove them from there at some point).
> > You should always use the value, which was used when the set was
> > created. Everything else make not much sense.
> >
> > Best regards,
> >
> > Bálint
> >
> >
> > On 22.11.22 05:24, Wu, Qisheng wrote:
> > > Dear Bálint,
> > >
> > > Thanks a lot for this explanation. I will definitely look more into
> > > tuning the compression radius during parameterization.
> > >
> > > I found that the problem can be solved by setting Li = "s" in
> > > the MaxAngularMomentum black for calculations with the DFTB+ 22.1 code.
> > > I used to set Li = "p" since Li was fitted with a Basis set of "2s2p",
> > > which is the only option available in MS. I am not sure which setting
> is
> > > more appropriate. Sorry for my poor understanding of this part. I
> > > appreciate it if you can point it out.
> > >
> > > I also tuned between S = "p" and S = "d" in the MaxAngularMomentum
> > > black. Here are some comparisons of the optimized lattice constants and
> > > bulk modulus of Li2S bulk:
> > > ----------------------------------
> > > ##settings                                       # lattice constant (a)
> > >        # bulk modulus
> > > DFTB+ 22.1, Li = "s", S = "p"           5.682 angstroms
>  46.6
> > GPa
> > > DFTB+ 22.1, Li = "s", S = "d"           5.651 angstroms
>  59.4
> > GPa
> > > DFTB+ 22.1, Li = "p", S = "d"           not working, as I mentioned....
> > > DFTB+ at MS, Li = "p", S = "d"           5.613 angstroms             62.0
> > GPa
> > > Ref: Materials Project data               5.720 angstroms
> > >   40.0 GPa
> > > -----------------------------------
> > >
> > > The skf parameter files are all same as before (see my previous
> > > message). It is seen that with Li = "s" and S = "p", the lattice
> > > constants and bulk modulus of Li2S bulk are well reproduced through
> > > calculations with the DFTB+ 22.1 code. But it does not give the correct
> > > Li-S bond distance in the Li2S molecule (2.30 angstroms vs 2.07
> > > angstroms from DFT data).
> > >
> > > Best regards,
> > > Qisheng Wu
> > >
> > >
> > >     Date: Thu, 17 Nov 2022 08:51:10 +0100
> > >     From: Bálint Aradi <aradi at uni-bremen.de <mailto:
> aradi at uni-bremen.de
> > >>
> > >     To: User list for DFTB+ related questions
> > >              <dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>>
> > >     Subject: Re: [DFTB-Plus-User] Failure in diagonalisation routine
> > >              ZHEEVR for Li-S systems
> > >     Message-ID: <aae55aeb-1858-1735-7e56-8819882cdc31 at uni-bremen.de
> > >     <mailto:aae55aeb-1858-1735-7e56-8819882cdc31 at uni-bremen.de>>
> > >     Content-Type: text/plain; charset="utf-8"; Format="flowed"
> > >
> > >     Dear Qisheng Wu,
> > >
> > >     what I meant is, that if you generate the parametrization yourself,
> > you
> > >     have control over the extent of the atomic orbitals via the wave
> > >     function compression radius. Setting it to a low value, will
> compress
> > >     the atomic orbitals and decrease their extent, while a high value
> > >     results in more delocalized atomic orbitals. Setting the wave
> > function
> > >     compression radius for Li higher (compressing it less) may make the
> > >     diagonalization of closely packed LiS structures more robust.
> > >
> > >     Best regards,
> > >
> > >     Bálint
> > >
> > >     On 16.11.22 20:33, Wu, Qisheng wrote:
> > >      > Dear Balint,
> > >      >
> > >      > Many thanks. But what do you mean by "decreasing/increasing the
> > basis
> > >      > function extend of the big/small element"? Sorry, I do not
> > >     understand
> > >      > this part. What exactly should I do about this?
> > >      >
> > >      > Best regards,
> > >      > Qisheng Wu
> > >      >
> > >      >
> > >      >
> > >      >     Message: 1
> > >      >     Date: Wed, 16 Nov 2022 08:32:58 +0100
> > >      >     From: Bálint Aradi <aradi at uni-bremen.de
> > >     <mailto:aradi at uni-bremen.de> <mailto:aradi at uni-bremen.de
> > >     <mailto:aradi at uni-bremen.de>>>
> > >      >     To: dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>>
> > >      >     Subject: Re: [DFTB-Plus-User]  Re: Failure in
> diagonalisation
> > >      >              routine ZHEEVR for Li-S systems
> > >      >     Message-ID:
> > >     <93b0eabb-b13f-ad86-f006-14cc51038777 at uni-bremen.de
> > >     <mailto:93b0eabb-b13f-ad86-f006-14cc51038777 at uni-bremen.de>
> > >      >     <mailto:93b0eabb-b13f-ad86-f006-14cc51038777 at uni-bremen.de
> > >     <mailto:93b0eabb-b13f-ad86-f006-14cc51038777 at uni-bremen.de>>>
> > >      >     Content-Type: text/plain; charset="utf-8"; Format="flowed"
> > >      >
> > >      >     Dear Qisheng Wu,
> > >      >
> > >      >     Probably your system is very much on the edge of
> > >     diagonalizability (if
> > >      >     such a word exists...), and the two different DFTB+ versions
> > use
> > >      >     different LAPACK implementation with slightly different
> > >     diagonalizer /
> > >      >     Cholesky-decomposer numerics, leading to different results.
> > When
> > >      >     putting
> > >      >     very "big" and very "small" elements in a tightly packed
> > >     solid, basis
> > >      >     dependence can become an issue. Usually,
> > >     decreasing/increasing the
> > >      >     basis
> > >      >     function extend of the big/small element can help to resolve
> > >     the issue.
> > >      >
> > >      >     Best regards,
> > >      >
> > >      >     Bálint
> > >      >
> > >      >
> > >      >
> > >      >     On 14.11.22 17:34, Wu, Qisheng wrote:
> > >      >      > Dear Martin,
> > >      >      >
> > >      >      > Thanks a lot for the comments. Here are my replies:
> > >      >      >
> > >      >      > I checked the skf.aux file, it shows
> "NotOrbitalResolved".
> > >      >      >
> > >      >      > I believe the geometry optimizations in both standalone
> > DFTB+
> > >      >     code and
> > >      >      > MS are working properly. The error actually occurred at
> > >     the very
> > >      >     initial
> > >      >      > step, so it has nothing to do with geometry
> optimizations.
> > >     The error
> > >      >      > also occurred when doing single-point energy
> calculations.
> > >      >      >
> > >      >      > For the fitting, I followed the procedure reported in a
> > >     previous
> > >      >     work
> > >      >      > (https://doi.org/10.1021/acs.jpcc.8b01839
> > >     <https://doi.org/10.1021/acs.jpcc.8b01839>
> > >      >     <https://doi.org/10.1021/acs.jpcc.8b01839
> > >     <https://doi.org/10.1021/acs.jpcc.8b01839>>
> > >      >      > <https://doi.org/10.1021/acs.jpcc.8b01839
> > >     <https://doi.org/10.1021/acs.jpcc.8b01839>
> > >      >     <https://doi.org/10.1021/acs.jpcc.8b01839
> > >     <https://doi.org/10.1021/acs.jpcc.8b01839>>>) conducted in our
> group
> > >      >     (Yue
> > >      >      > Qi group @ Brown Univ.), in which the parameters were
> > >     fitted as an
> > >      >      > extension of the mio set with the MS parameterization
> > >     tools. In that
> > >      >      > work, systematic validations were presented for the
> > >     Li-containing
> > >      >      > systems, including Li metal, Li-containing inorganic
> > >     crystals (LiH,
> > >      >      > Li2O, and Li2CO3), molecular species (LiOH, LiCH3, et
> > >     al.), and some
> > >      >      > surface and interface systems. Those fitted parameters
> > >     (both the
> > >      >      > electronic parameters of Li and the repulsive potentials)
> > >     worked
> > >      >      > very well. At that time, there was no LIB 2019 yet. I do
> > >     not want to
> > >      >      > make too many changes while trying to extend the
> > >     parameterization
> > >      >     set to
> > >      >      > include S and maybe also other elements.
> > >      >      >
> > >      >      > For band structure validations of li metal and Li2S bulk,
> > >     please
> > >      >     see the
> > >      >      > figure attached or through the following link:
> > >      >      >
> > >      >
> > >
> >
> https://drive.google.com/file/d/1LSmYELMtIBQBlOlXgZjnACHUv208EnxU/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LSmYELMtIBQBlOlXgZjnACHUv208EnxU/view?usp=share_link
> >
> > <
> >
> https://drive.google.com/file/d/1LSmYELMtIBQBlOlXgZjnACHUv208EnxU/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LSmYELMtIBQBlOlXgZjnACHUv208EnxU/view?usp=share_link
> >>
> > <
> >
> https://drive.google.com/file/d/1LSmYELMtIBQBlOlXgZjnACHUv208EnxU/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LSmYELMtIBQBlOlXgZjnACHUv208EnxU/view?usp=share_link
> >
> > <
> >
> https://drive.google.com/file/d/1LSmYELMtIBQBlOlXgZjnACHUv208EnxU/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LSmYELMtIBQBlOlXgZjnACHUv208EnxU/view?usp=share_link
> > >>>
> > >      >      >
> > >      >      > In my new fitting, the electronic parameters are
> > >     slightly revised
> > >      >      > compared to what was reported in our previous work
> > >      >      > (https://doi.org/10.1021/acs.jpcc.8b01839
> > >     <https://doi.org/10.1021/acs.jpcc.8b01839>
> > >      >     <https://doi.org/10.1021/acs.jpcc.8b01839
> > >     <https://doi.org/10.1021/acs.jpcc.8b01839>>
> > >      >      > <https://doi.org/10.1021/acs.jpcc.8b01839
> > >     <https://doi.org/10.1021/acs.jpcc.8b01839>
> > >      >     <https://doi.org/10.1021/acs.jpcc.8b01839
> > >     <https://doi.org/10.1021/acs.jpcc.8b01839>>>), but you can see
> that
> > the
> > >      >      > band structures near the Fermi level of Li metal are
> still
> > >     well
> > >      >      > reproduced. The band structures of the valence bands of
> > Li2S
> > >      >     calculated
> > >      >      > with DFTB agree with Dmol3 calculations as well.
> > >      >      >
> > >      >      > I did not use dispersion correction while calculating the
> > band
> > >      >      > structures with DFTB and Dmol3 in MS. I tested on
> > dispersion
> > >      >     correction
> > >      >      > (LJ, UFF parameters) while doing geometry optimizations
> > >     with the
> > >      >      > standalone DFTB+ code, and found that it makes little
> > >     difference.
> > >      >      >
> > >      >      > Thanks again for your time.
> > >      >      >
> > >      >      > Best regards,
> > >      >      > Qisheng Wu
> > >      >      >
> > >      >      >
> > >      >      > On Fri, Nov 11, 2022 at 5:05 AM
> > >      >      > <dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de>>
> > >      >      > <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de>>>>
> wrote:
> > >      >      >
> > >      >      >     -----------------------------
> > >      >      >
> > >      >      >     Message: 2
> > >      >      >     Date: Fri, 11 Nov 2022 10:04:42 +0000
> > >      >      >     From: PERSSON Martin <Martin.PERSSON at 3ds.com
> > >     <mailto:Martin.PERSSON at 3ds.com>
> > >      >     <mailto:Martin.PERSSON at 3ds.com <mailto:
> Martin.PERSSON at 3ds.com
> > >>
> > >      >      >     <mailto:Martin.PERSSON at 3ds.com
> > >     <mailto:Martin.PERSSON at 3ds.com> <mailto:Martin.PERSSON at 3ds.com
> > >     <mailto:Martin.PERSSON at 3ds.com>>>>
> > >      >      >     To: User list for DFTB+ related questions
> > >      >      >              <dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>>
> > >      >      >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>>>>
> > >      >      >     Subject: Re: [DFTB-Plus-User] Failure in
> > >     diagonalisation routine
> > >      >      >              ZHEEVR for Li-S systems
> > >      >      >     Message-ID: <
> 1c5596207e8348d49f887df843c9c81a at 3ds.com
> > >     <mailto:1c5596207e8348d49f887df843c9c81a at 3ds.com>
> > >      >     <mailto:1c5596207e8348d49f887df843c9c81a at 3ds.com
> > >     <mailto:1c5596207e8348d49f887df843c9c81a at 3ds.com>>
> > >      >      >     <mailto:1c5596207e8348d49f887df843c9c81a at 3ds.com
> > >     <mailto:1c5596207e8348d49f887df843c9c81a at 3ds.com>
> > >      >     <mailto:1c5596207e8348d49f887df843c9c81a at 3ds.com
> > >     <mailto:1c5596207e8348d49f887df843c9c81a at 3ds.com>>>>
> > >      >      >     Content-Type: text/plain; charset="utf-8"
> > >      >      >
> > >      >      >     Dear Qisheng Wu,
> > >      >      >
> > >      >      >     If you extended the MIO library “OrbitalResolvedScc”
> > >     should
> > >      >     be set
> > >      >      >     to “No”. The MS DFTB+ parameterization tools ensure
> > that
> > >      >     these type
> > >      >      >     of settings are consistent when you extend
> parameters.
> > You
> > >      >     can what
> > >      >      >     settings should be used in the skf.aux file in the
> > >     library.
> > >      >      >
> > >      >      >     MS has its own drivers for Geometry optimization,
> > Dynamics
> > >      >     etc. so
> > >      >      >     the optimizer likely takes a different path to the
> > >     optimized
> > >      >     geometry.
> > >      >      >     Even though the MS 2020 version of DFTB+ is older it
> > >     uses the
> > >      >     same
> > >      >      >     eigenvalue solvers. The only difference I noticed
> when
> > >      >     updating was
> > >      >      >     that we got slightly different geometries and
> dynamics
> > >      >     results since
> > >      >      >     the force evaluation has been updated, but those
> > >     differences was
> > >      >      >     very small.
> > >      >      >
> > >      >      >     When you did the optimization did you fit the
> > >     electronic settings
> > >      >      >     for Li to the Li band structure using the scripted
> > >     tools in MS?
> > >      >      >     Have you checked the band structure for the Li2S and
> > >     did you run
> > >      >      >     with or without dispersion correction?
> > >      >      >
> > >      >      >     Finally why did you extend the mio library? I think
> > >     the “LIB
> > >      >     2019”
> > >      >      >     library, containing Li-C-H-N-O-P-F, is available in
> MS
> > >     2020.
> > >      >     It was
> > >      >      >     mainly fitted and validated against small molecules
> so
> > I
> > >      >     can’t make
> > >      >      >     promises about how it will perform for solids. But
> > then so
> > >      >     was mio.
> > >      >      >
> > >      >      >     Best Regards,
> > >      >      >     Martin PERSSON
> > >      >      >     BIOVIA Scientific R&D Development Manager
> > >      >      >
> > >      >      >     Dear Dr. Aradi,
> > >      >      >
> > >      >      >     Thanks for your comment, but adding ShellResolvedScc
> =
> > Yes
> > >      >     does not
> > >      >      >     solve the problem (DFTB+ 22.1).
> > >      >      >
> > >      >      >     Adding OrbitalResolvedScc = Yes to simulation with
> > >     DFTB+ 17.1
> > >      >     does
> > >      >      >     not solve the problem as well.
> > >      >      >
> > >      >      >     In terms of the version of DFTB+ in Materials Studio
> > 2020,
> > >      >     here is
> > >      >      >     the reply from people who work for Dassault Systemes:
> > >      >      >
> > >      >      >     "It is a modified version of the  r4729 version of
> the
> > >     DFTB+
> > >      >     code.
> > >      >      >     It's from 2015. There is a few years gap in the
> > >     updates of DFTB+
> > >      >      >     since their rewrite of the code did not support all
> > >     the features
> > >      >      >     that were exposed in the MS version. The current
> > >     release of
> > >      >     MS has
> > >      >      >     an up to date version of DFTB+."
> > >      >      >
> > >      >      >     I will also ask them to see if they can help solve
> > >     this problem.
> > >      >      >     Thanks again.
> > >      >      >
> > >      >      >     Best regards,
> > >      >      >     Qisheng Wu
> > >      >      >
> > >      >      >
> > >      >      >     On Wed, Nov 9, 2022 at 4:52 AM Bálint Aradi
> > >      >     <aradi at uni-bremen.de <mailto:aradi at uni-bremen.de>
> > >     <mailto:aradi at uni-bremen.de <mailto:aradi at uni-bremen.de>>
> > >      >      >     <mailto:aradi at uni-bremen.de <mailto:
> > aradi at uni-bremen.de>
> > >      >     <mailto:aradi at uni-bremen.de
> > >     <mailto:aradi at uni-bremen.de>>><mailto:aradi at uni-bremen.de
> > >     <mailto:aradi at uni-bremen.de>
> > >      >     <mailto:aradi at uni-bremen.de <mailto:aradi at uni-bremen.de>>
> > >      >      >     <mailto:aradi at uni-bremen.de
> > >     <mailto:aradi at uni-bremen.de> <mailto:aradi at uni-bremen.de
> > >     <mailto:aradi at uni-bremen.de>>>>>
> > >      >     wrote:
> > >      >      >     The only difference I can see, is that you commented
> > out
> > >      >      >     OrbitalResolvedScc in your input (which was changed
> to
> > >      >     ShellResolvedScc
> > >      >      >     at some point). That would be important to add to get
> > >     similar
> > >      >     results as
> > >      >      >     with MS.
> > >      >      >
> > >      >      >     As for periodic versus non-periodic: The overlap of
> > >     the basis
> > >      >     functions
> > >      >      >     is in the periodic case bigger, so if your system is
> > >     on the
> > >      >     edge of
> > >      >      >     having a linearly dependent basis set, chances are
> > bigger,
> > >      >     that you get
> > >      >      >     a problem in the periodic case.
> > >      >      >
> > >      >      >     Cheers,
> > >      >      >
> > >      >      >     Bálint
> > >      >      >
> > >      >      >
> > >      >      >     On 08.11.22 15:37, Wu, Qisheng wrote:
> > >      >      >      > Dear Dr. Bálint Aradi,
> > >      >      >      >
> > >      >      >      > Many thanks for the quick reply. You are right
> that
> > >     the S is
> > >      >      >     supposed to
> > >      >      >      > be with "d" as the maximal angular shell in the
> > >     mio-set. I
> > >      >     made the
> > >      >      >      > change and re-run the geometry optimizations.
> > >      >     Unfortunately, this
> > >      >      >     does
> > >      >      >      > not solve the problem. For the Li2S molecule, It
> > >     turns out
> > >      >     that
> > >      >      >     it makes
> > >      >      >      > very little difference in terms of Li-S bond
> length
> > >     (2.005
> > >      >      >     angstroms vs
> > >      >      >      > 2.002 angstroms). But of course, "d" still should
> > >     be used
> > >      >     anyway.
> > >      >      >      >
> > >      >      >      > I have also looked at the input file generated
> > >     within MS and
> > >      >      >     attached it
> > >      >      >      > to this email (Li2S_tetra.hsd). The version of
> > >     DFTB+ in MS
> > >      >     2020
> > >      >      >     might be
> > >      >      >      > different (I do not know what version it is), and
> > there
> > >      >     are some
> > >      >      >      > keywords that I did not previously use in my
> input.
> > >     The Driver
> > >      >      >     section
> > >      >      >      > is also empty, whose possible reason is that MS
> > >     uses its own
> > >      >      >     driver to
> > >      >      >      > conduct geometry optimizations (it's just my
> > >     guess). After
> > >      >      >     tailoring my
> > >      >      >      > own inputs based on what I found in the input from
> > MS
> > >      >     (dftb_in.hsd as
> > >      >      >      > attached), I was still not able to solve the
> > problem.
> > >      >      >      >
> > >      >      >      > What I do not understand is that the calculation
> > >     works for
> > >      >     the Li2S
> > >      >      >      > molecule but not for the Li2S bulk. It's really
> > >     puzzling.
> > >      >     I hope this
> > >      >      >      > issue could be fixed in the end.
> > >      >      >      >
> > >      >      >      > By the way, I have tested using different versions
> > of
> > >      >     DFTB+ (e.g.,
> > >      >      >      > 17.1), and the same error showed up for geometry
> > >      >     optimization of the
> > >      >      >      > Li2S bulk, but not for the Li2S molecule.
> > >      >      >      >
> > >      >      >      > Thanks again.
> > >      >      >      >
> > >      >      >      > Best regards,
> > >      >      >      > Qisheng Wu
> > >      >      >      >
> > >      >      >      >
> > >      >      >      > On Tue, Nov 8, 2022 at 6:00 AM
> > >      >      >      > <dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de>>
> > >      >      >
> > >       <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> >>><mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de>> <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de>>>>
> > >      >      >      >
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de>>
> > >      >      >
> > >       <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> >>><mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de>> <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de>>>>>> wrote:
> > >      >      >      >
> > >      >      >      >     Send DFTB-Plus-User mailing list submissions
> to
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> > >      >      >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>>><mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de>> <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de>>>>
> > >      >      >      >
> > >       <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>>
> > >      >      >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>>><mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de>> <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de>>>>>
> > >      >      >      >
> > >      >      >      >     To subscribe or unsubscribe via the World Wide
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> > >      >      >
> > >      >
> > >
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> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> >>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
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> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> >>>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
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> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> >>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
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> > <
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> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > >>>>
> > >      >      >      >
> > >      >      >      >     or, via email, send a message with subject or
> > body
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> > >      >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de>>
> > >      >      >
> > >       <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> >>><mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de>> <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de>>>>
> > >      >      >      >
> > >      >       <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de>>
> > >      >      >
> > >       <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-request at mailman.zfn.uni-bremen.de
> >>><mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de>> <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-request at mailman.zfn.uni-bremen.de>>>>>
> > >      >      >      >
> > >      >      >      >     You can reach the person managing the list at
> > >      >      >      > dftb-plus-user-owner at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-owner at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user-owner at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-owner at mailman.zfn.uni-bremen.de>>
> > >      >      >     <mailto:
> dftb-plus-user-owner at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-owner at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user-owner at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-owner at mailman.zfn.uni-bremen.de>>><mailto:
> > dftb-plus-user-owner at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-owner at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user-owner at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-owner at mailman.zfn.uni-bremen.de>> <mailto:
> > dftb-plus-user-owner at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-owner at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user-owner at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-owner at mailman.zfn.uni-bremen.de>>>>
> > >      >      >      >
> > >       <mailto:dftb-plus-user-owner at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-owner at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user-owner at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-owner at mailman.zfn.uni-bremen.de>>
> > >      >      >     <mailto:
> dftb-plus-user-owner at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-owner at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user-owner at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user-owner at mailman.zfn.uni-bremen.de>>><mailto:
> > dftb-plus-user-owner at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-owner at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user-owner at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-owner at mailman.zfn.uni-bremen.de>> <mailto:
> > dftb-plus-user-owner at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-owner at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user-owner at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user-owner at mailman.zfn.uni-bremen.de>>>>>
> > >      >      >      >
> > >      >      >      >     When replying, please edit your Subject line
> so
> > >     it is more
> > >      >      >     specific
> > >      >      >      >     than "Re: Contents of DFTB-Plus-User
> digest..."
> > >      >      >      >
> > >      >      >      >
> > >      >      >      >     Today's Topics:
> > >      >      >      >
> > >      >      >      >         1. Re: Failure in diagonalisation routine
> > >     ZHEEVR
> > >      >     for Li-S
> > >      >      >      >            systems (Bálint Aradi)
> > >      >      >      >
> > >      >      >      >
> > >      >      >      >
> > >      >      >
> > >      >
> > >
> >  ----------------------------------------------------------------------
> > >      >      >      >
> > >      >      >      >     Message: 1
> > >      >      >      >     Date: Mon, 7 Nov 2022 16:12:28 +0100
> > >      >      >      >     From: Bálint Aradi <aradi at uni-bremen.de
> > >     <mailto:aradi at uni-bremen.de>
> > >      >     <mailto:aradi at uni-bremen.de <mailto:aradi at uni-bremen.de>>
> > >      >      >     <mailto:aradi at uni-bremen.de <mailto:
> > aradi at uni-bremen.de>
> > >      >     <mailto:aradi at uni-bremen.de
> > >     <mailto:aradi at uni-bremen.de>>><mailto:aradi at uni-bremen.de
> > >     <mailto:aradi at uni-bremen.de>
> > >      >     <mailto:aradi at uni-bremen.de <mailto:aradi at uni-bremen.de>>
> > >      >      >     <mailto:aradi at uni-bremen.de
> > >     <mailto:aradi at uni-bremen.de> <mailto:aradi at uni-bremen.de
> > >     <mailto:aradi at uni-bremen.de>>>>
> > >      >     <mailto:aradi at uni-bremen.de <mailto:aradi at uni-bremen.de>
> > >     <mailto:aradi at uni-bremen.de <mailto:aradi at uni-bremen.de>>
> > >      >      >     <mailto:aradi at uni-bremen.de <mailto:
> > aradi at uni-bremen.de>
> > >      >     <mailto:aradi at uni-bremen.de
> > >     <mailto:aradi at uni-bremen.de>>><mailto:aradi at uni-bremen.de
> > >     <mailto:aradi at uni-bremen.de>
> > >      >     <mailto:aradi at uni-bremen.de <mailto:aradi at uni-bremen.de>>
> > >      >      >     <mailto:aradi at uni-bremen.de
> > >     <mailto:aradi at uni-bremen.de> <mailto:aradi at uni-bremen.de
> > >     <mailto:aradi at uni-bremen.de>>>>>>
> > >      >      >      >     To: dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>>
> > >      >      >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>>><mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de>> <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de>>>>
> > >      >      >      >
> > >       <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>>
> > >      >      >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de
> > >     <mailto:dftb-plus-user at mailman.zfn.uni-bremen.de>>><mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de>> <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de> <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de <mailto:
> > dftb-plus-user at mailman.zfn.uni-bremen.de>>>>>
> > >      >      >      >     Subject: Re: [DFTB-Plus-User] Failure in
> > >      >     diagonalisation routine
> > >      >      >      >              ZHEEVR for Li-S systems
> > >      >      >      >     Message-ID:
> > >      >      >     <8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de
> > >     <mailto:8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de>
> > >      >     <mailto:8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de
> > >     <mailto:8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de>>
> > >      >      >
> > >       <mailto:8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de
> > >     <mailto:8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de>
> > >      >     <mailto:8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de
> > >     <mailto:8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de
> > >>><mailto:8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de <mailto:
> > 8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de> <mailto:
> > 8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de <mailto:
> > 8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de>> <mailto:
> > 8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de <mailto:
> > 8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de> <mailto:
> > 8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de <mailto:
> > 8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de>>>>
> > >      >      >      >
> > >      >       <mailto:
> 8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de
> > >     <mailto:8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de>
> > >      >     <mailto:8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de
> > >     <mailto:8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de>>
> > >      >      >
> > >       <mailto:8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de
> > >     <mailto:8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de>
> > >      >     <mailto:8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de
> > >     <mailto:8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de
> > >>><mailto:8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de <mailto:
> > 8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de> <mailto:
> > 8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de <mailto:
> > 8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de>> <mailto:
> > 8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de <mailto:
> > 8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de> <mailto:
> > 8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de <mailto:
> > 8d8e2f4f-6368-a719-f281-d263b107c054 at uni-bremen.de>>>>>>
> > >      >      >      >     Content-Type: text/plain; charset="utf-8";
> > >     Format="flowed"
> > >      >      >      >
> > >      >      >      >     Dear Qisheng Wu,
> > >      >      >      >
> > >      >      >      >     The DFTB+ in MS is identical to the open
> source
> > >     version,
> > >      >      >     therefore,
> > >      >      >      >     I am
> > >      >      >      >     a little bit puzzled, why you get different
> > >     behavior
> > >      >     for the bulk
> > >      >      >      >     calculation.
> > >      >      >      >
> > >      >      >      >     Check, whether the dftb+ input file generated
> > >     by MS is
> > >      >      >     equivalent to
> > >      >      >      >     yours. My guess would be the maximal angular
> > >     momenta.
> > >      >      >     Actually, in the
> > >      >      >      >     mio-set the S is supposed to be with "d" as
> > maximal
> > >      >     angular
> > >      >      >     shell (and
> > >      >      >      >     you use "p" instead). Also probably MS uses
> > >     only "s"
> > >      >     for the
> > >      >      >     Li and not
> > >      >      >      >     "p" as in your input?
> > >      >      >      >
> > >      >      >      >     Best regards,
> > >      >      >      >
> > >      >      >      > Bálint
> > >      >      >      >
> > >      >      >      >
> > >      >      >      >     On 07.11.22 15:47, Wu, Qisheng wrote:
> > >      >      >      >      > Dear DFTB+ developers,
> > >      >      >      >      >
> > >      >      >      >      > I am currently working on a Li-S system and
> > >     fitted
> > >      >     Li-Li
> > >      >      >     and L-S
> > >      >      >      >      > parameters as an extension of the /mio/ set
> > >     using
> > >      >     the DFTB+
> > >      >      >      >     module and
> > >      >      >      >      > parameterization tools as implemented in
> the
> > >      >     Materials Studio
> > >      >      >      >     software.
> > >      >      >      >      > S-S is directly taken from the /mio/ set.
> To
> > >     verify the
> > >      >      >      >     parameters, I
> > >      >      >      >      > first conducted geometry optimizations of
> > >     Li2S bulk
> > >      >     and Li2S
> > >      >      >      >     molecule,
> > >      >      >      >      > which ran very well through the DFTB+
> module
> > >     in the
> > >      >      >     Materials Studio
> > >      >      >      >      > software.
> > >      >      >      >      >
> > >      >      >      >      > Then I switched to DFTB+ 22.1 code
> > (precompiled
> > >      >     executable for
> > >      >      >      >     x86_64),
> > >      >      >      >      > which I will need to use for large-scale
> > >      >     simulations. The
> > >      >      >     geometry
> > >      >      >      >      > optimization of the Li2S molecule worked
> > >     very well, but
> > >      >      >     that of
> > >      >      >      >     the L2S
> > >      >      >      >      > bulk failed, with the error information:
> > >      >      >      >      >
> > >      >      >      >      > "-> Failure in diagonalisation routine
> > ZHEEVR,
> > >      >     unable to
> > >      >      >     complete
> > >      >      >      >      > Cholesky factorization of B     85"
> > >      >      >      >      >
> > >      >      >      >      > I checked some previous messages in this
> > email
> > >      >     list, and
> > >      >      >     am aware
> > >      >      >      >     that
> > >      >      >      >      > this could be due to unphysical geometry.
> > >     But I do not
> > >      >      >     think this
> > >      >      >      >     is the
> > >      >      >      >      > case for my simulation since it worked well
> > at
> > >      >     least for
> > >      >      >     the Li2S
> > >      >      >      >     molecule.
> > >      >      >      >      >
> > >      >      >      >      > I appreciate it if anyone can help address
> > >     this issue,
> > >      >      >     which will be
> > >      >      >      >      > very helpful for me to continue my research
> > >     project. I
> > >      >      >     have put
> > >      >      >      >     all the
> > >      >      >      >      > inputs (dftb_in.hsd), outputs (out), and
> > >     parameter
> > >      >     files
> > >      >      >     (*skf)
> > >      >      >      >     in my
> > >      >      >      >      > google drive. Feel free to download that
> > >     using the
> > >      >     link below:
> > >      >      >      >      >
> > >      >      >      >      >
> > >      >      >      >
> > >      >      >
> > >      >
> > >
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> >
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> >>
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> >
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> >>>
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> >
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> >>
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> >
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> >>>>
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> >
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> >>
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> >
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> >>>
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> >
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> >>
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> >
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> > <
> >
> https://drive.google.com/file/d/1LL8GHzfI8pH4Nlr2ZJ8IN4q3xTVpQmy1/view?usp=share_link
> > >>>>>
> > >      >      >      >      >
> > >      >      >      >      > Best regards,
> > >      >      >      >      > Qisheng Wu
> > >      >      >      >      >
> > >      >      >      >      >
> > _______________________________________________
> > >      >      >      >      > DFTB-Plus-User mailing list
> > >      >      >      >      > DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>>
> > >      >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>>><mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de> <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de>> <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de> <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de>>>>
> > >      >      >      >
> > >       <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>>
> > >      >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>>><mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de> <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de>> <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de> <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de>>>>>
> > >      >      >      >      >
> > >      >      >      >
> > >      >      >
> > >      >
> > >
> >
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> >>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> >>>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> >>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > >>>>
> > >      >      >      >
> > >      >      >      >     --
> > >      >      >      >     Dr. Bálint Aradi
> > >      >      >      >     Bremen Center for Computational Materials
> > Science,
> > >      >     University
> > >      >      >     of Bremen
> > >      >      >      >
> http://www.bccms.uni-bremen.de/cms/people/b-aradi/
> > >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/>
> > >      >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/
> > >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/>>
> > >      >      >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/
> > >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/>
> > >      >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/
> > >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/>>>
> > >      >      >      >
> > >       <http://www.bccms.uni-bremen.de/cms/people/b-aradi/
> > >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/>
> > >      >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/
> > >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/>>
> > >      >      >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/
> > >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/>
> > >      >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/
> > >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/>>>>
> > >      >      >      >
> > >      >      >      >
> > >      >      >      >     -------------- next part --------------
> > >      >      >      >     A non-text attachment was scrubbed...
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> > >      >      >      >     Desc: OpenPGP digital signature
> > >      >      >      >     URL:
> > >      >      >      >
> > >      >      >
> > >      >
> > >       <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221107/2202d405/attachment-0001.sig
> > <
> >
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> >
> > <
> >
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> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221107/2202d405/attachment-0001.sig
> >>
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221107/2202d405/attachment-0001.sig
> > <
> >
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> >
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221107/2202d405/attachment-0001.sig
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221107/2202d405/attachment-0001.sig
> >>>
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221107/2202d405/attachment-0001.sig
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221107/2202d405/attachment-0001.sig
> >
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221107/2202d405/attachment-0001.sig
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221107/2202d405/attachment-0001.sig
> >>
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221107/2202d405/attachment-0001.sig
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221107/2202d405/attachment-0001.sig
> >
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221107/2202d405/attachment-0001.sig
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221107/2202d405/attachment-0001.sig
> > >>>>>
> > >      >      >      >
> > >      >      >      >     ------------------------------
> > >      >      >      >
> > >      >      >      >     Subject: Digest Footer
> > >      >      >      >
> > >      >      >      >
>  _______________________________________________
> > >      >      >      >     DFTB-Plus-User mailing list
> > >      >      >      > DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>>
> > >      >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>>><mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de> <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de>> <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de> <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de>>>>
> > >      >      >      >
> > >       <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>>
> > >      >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>>><mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de> <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de>> <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de> <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de>>>>>
> > >      >      >      >
> > >      >      >
> > >      >
> > >
> >
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> >>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> >>>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> >>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > >>>>
> > >      >      >      >
> > >      >      >      >
> > >      >      >      >     ------------------------------
> > >      >      >      >
> > >      >      >      >     End of DFTB-Plus-User Digest, Vol 99, Issue 6
> > >      >      >      >     *********************************************
> > >      >      >      >
> > >      >      >      >
> > >      >      >      > _______________________________________________
> > >      >      >      > DFTB-Plus-User mailing list
> > >      >      >      > DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>>
> > >      >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>>><mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de> <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de>> <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de> <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de <mailto:
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de>>>>
> > >      >      >      >
> > >      >      >
> > >      >
> > >
> >
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> >>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > >>>
> > >      >      >
> > >      >      >     --
> > >      >      >     Dr. Bálint Aradi
> > >      >      >     Bremen Center for Computational Materials Science,
> > >     University
> > >      >     of Bremen
> > >      >      > http://www.bccms.uni-bremen.de/cms/people/b-aradi/
> > >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/>
> > >      >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/
> > >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/>>
> > >      >      >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/
> > >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/>
> > >      >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/
> > >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/>>>
> > >      >      >
> > >      >      >
> > >      >      >     This email and any attachments are intended solely
> for
> > >     the use of
> > >      >      >     the individual or entity to whom it is addressed and
> > >     may be
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> > >      >      >     If you are not one of the named recipients or have
> > >     received this
> > >      >      >     email in error,
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> > >      >      >     (i) you should not read, disclose, or copy it,
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> > >      >      >     (ii) please notify sender of your receipt by reply
> > >     email and
> > >      >     delete
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> > >      >      >     Please be informed that your personal data are
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> > >      >      >     <https://www.3ds.com/privacy-policy/contact/
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> > >      >     <https://www.3ds.com/privacy-policy/contact/
> > >     <https://www.3ds.com/privacy-policy/contact/>>>
> > >      >      >
> > >      >      >     -------------- next part --------------
> > >      >      >     An HTML attachment was scrubbed...
> > >      >      >     URL:
> > >      >      >
> > >      >
> > >       <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221111/606dfc0e/attachment.htm
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221111/606dfc0e/attachment.htm
> >
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221111/606dfc0e/attachment.htm
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221111/606dfc0e/attachment.htm
> >>
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221111/606dfc0e/attachment.htm
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221111/606dfc0e/attachment.htm
> >
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221111/606dfc0e/attachment.htm
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221111/606dfc0e/attachment.htm
> > >>>>
> > >      >      >
> > >      >      >     ------------------------------
> > >      >      >
> > >      >      >     Subject: Digest Footer
> > >      >      >
> > >      >      >     _______________________________________________
> > >      >      >     DFTB-Plus-User mailing list
> > >      >      > DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>>
> > >      >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>>>
> > >      >      >
> > >      >
> > >
> >
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> >>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > >>>
> > >      >      >
> > >      >      >
> > >      >      >     ------------------------------
> > >      >      >
> > >      >      >     End of DFTB-Plus-User Digest, Vol 99, Issue 11
> > >      >      >     **********************************************
> > >      >      >
> > >      >      >
> > >      >      > _______________________________________________
> > >      >      > DFTB-Plus-User mailing list
> > >      >      > DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>>
> > >      >      >
> > >      >
> > >
> >
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > >>
> > >      >
> > >      >     --
> > >      >     Dr. Bálint Aradi
> > >      >     Bremen Center for Computational Materials Science,
> University
> > >     of Bremen
> > >      > http://www.bccms.uni-bremen.de/cms/people/b-aradi/
> > >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/>
> > >      >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/
> > >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/>>
> > >      >
> > >      >
> > >      >     -------------- next part --------------
> > >      >     A non-text attachment was scrubbed...
> > >      >     Name: OpenPGP_signature
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> > >      >     Size: 840 bytes
> > >      >     Desc: OpenPGP digital signature
> > >      >     URL:
> > >      >
> > >       <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221116/d0d86dc8/attachment.sig
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221116/d0d86dc8/attachment.sig
> >
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221116/d0d86dc8/attachment.sig
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221116/d0d86dc8/attachment.sig
> > >>>
> > >      >
> > >      >     ------------------------------
> > >      >
> > >      >     Subject: Digest Footer
> > >      >
> > >      >     _______________________________________________
> > >      >     DFTB-Plus-User mailing list
> > >      > DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>
> > >      >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>>
> > >      >
> > >
> >
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user>
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > >>
> > >      >
> > >      >
> > >      >     ------------------------------
> > >      >
> > >      >     End of DFTB-Plus-User Digest, Vol 99, Issue 15
> > >      >     **********************************************
> > >      >
> > >
> > >     --
> > >     Dr. Bálint Aradi
> > >     Bremen Center for Computational Materials Science, University of
> > Bremen
> > >     http://www.bccms.uni-bremen.de/cms/people/b-aradi/
> > >     <http://www.bccms.uni-bremen.de/cms/people/b-aradi/>
> > >
> > >
> > >     -------------- next part --------------
> > >     A non-text attachment was scrubbed...
> > >     Name: OpenPGP_signature
> > >     Type: application/pgp-signature
> > >     Size: 840 bytes
> > >     Desc: OpenPGP digital signature
> > >     URL:
> > >     <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221117/2c1f1c59/attachment.sig
> > <
> >
> http://mailman.zfn.uni-bremen.de/pipermail/dftb-plus-user/attachments/20221117/2c1f1c59/attachment.sig
> > >>
> > >
> > >     ------------------------------
> > >
> > >     Subject: Digest Footer
> > >
> > >     _______________________________________________
> > >     DFTB-Plus-User mailing list
> > >     DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >     <mailto:DFTB-Plus-User at mailman.zfn.uni-bremen.de>
> > >
> >
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > <
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> > >
> > >
> > >
> > >     ------------------------------
> > >
> > >     End of DFTB-Plus-User Digest, Vol 99, Issue 20
> > >     **********************************************
> > >
> > >
> > > _______________________________________________
> > > DFTB-Plus-User mailing list
> > > DFTB-Plus-User at mailman.zfn.uni-bremen.de
> > >
> >
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> >
> > --
> > Dr. Bálint Aradi
> > Bremen Center for Computational Materials Science, University of Bremen
> > http://www.bccms.uni-bremen.de/cms/people/b-aradi/
> >
> >
> > -------------- next part --------------
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> > URL: <
> >
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> > >
> >
> > ------------------------------
> >
> > Subject: Digest Footer
> >
> > _______________________________________________
> > DFTB-Plus-User mailing list
> > DFTB-Plus-User at mailman.zfn.uni-bremen.de
> >
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
> >
> >
> > ------------------------------
> >
> > End of DFTB-Plus-User Digest, Vol 99, Issue 25
> > **********************************************
> >
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>
> ------------------------------
>
> Subject: Digest Footer
>
> _______________________________________________
> DFTB-Plus-User mailing list
> DFTB-Plus-User at mailman.zfn.uni-bremen.de
> https://mailman.zfn.uni-bremen.de/cgi-bin/mailman/listinfo/dftb-plus-user
>
>
> ------------------------------
>
> End of DFTB-Plus-User Digest, Vol 99, Issue 31
> **********************************************
>
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